发明名称 OPTICALLY ACTIVE CYCLIC ETHER COMPOUND
摘要 PROBLEM TO BE SOLVED: To obtain the subject new compound useful as a reagent for optical resolution or an asymmetric reaction reagent capable of removing a salt content in an aqueous solution and an organic solvent by a simple operation and inexpensively mass-producing desalted solvent and having high generality not depending on molecular structure of racemic modification. SOLUTION: This compound is represented by formula I [R1 is H, etc.; R2 is H, etc.; Z1 is O, etc.; Z2 is O, etc.; (m) is 1 or 2; (n) is 0-7], e.g. (1R,2R)-O-[(1,2- diphenyl-1,2-ethanedioxy)borane], N-(N'-methacryloyl)-7,13-diaza-15- crown-5]phthalamide ester. The compound of formula I is obtained as a polymer by acylating, e.g. a compound of formula II, further acrylating or alkylating the resultant compound and subjecting the resultant compound to coupling to afford a monomer of borate substance and subjecting the monomer to asymmetric addition polymerization reaction.
申请公布号 JPH10212279(A) 申请公布日期 1998.08.11
申请号 JP19970131083 申请日期 1997.05.21
申请人 KASHIHARA HIROSHI 发明人 KASHIHARA HIROSHI
分类号 C07D323/00;B01J43/00;C02F1/42;C07B57/00;C07B61/00;C07D273/00;C07F5/02;(IPC1-7):C07D273/00 主分类号 C07D323/00
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