PROCESS FOR PRODUCING CYCLOPENTADIENYL METAL SALTS AND PROCESS FOR PRODUCING CYCLOPENTADIENE DERIVATIVES BY UTILIZING THE SAME
摘要
A process for producing cyclopentadienyl metal salts which comprises reacting a cyclopentadiene derivative with a metal hydride in the presence of an amine compound; and a process for producing cyclopentadiene derivatives represented by general formula (3) by utilizing this reaction. In said formula, A represents a Group 16 element of the Periodic Table; B represents a Group 14 element; R<1> to R<6> each represents alkyl, etc.; and R<7> represents a hydrocarbon group or a trisubstituted silyl. By using these processes, not only a variety of cyclopentadienyl metal salts but cyclopentadiene derivatives can be produced in high yields with high conversions without using an expensive reagent or low-temperature facilities.
申请公布号
WO9830567(A1)
申请公布日期
1998.07.16
申请号
WO1998JP00110
申请日期
1998.01.14
申请人
SUMITOMO CHEMICAL COMPANY, LIMITED;ODA, YOSHIAKI;YAMAUCHI, KAZUHIRO;HANAOKA, HIDENORI;SOUDA, HIROSHI