摘要 |
<p>A method of controlling the olefin polymerization activity of an unsupported, liquid form catalyst composition prepared by contacting a single site catalyst precursor with an activating cocatalyst outside of a polymerization reactor is provided. The method comprises adjusting at least one of: a) the period of time the single site catalyst precursor and the activating cocatalyst are contacted; b) the concentrations of the single site catalyst precursor and the activating cocatalyst during contacting; c) the mole ratio of the single site catalyst precursor to the activating cocatalyst during contacting; d) the temperature during contacting; and e) the degree of mixing of the single site catalyst precursor and the activating cocatalyst.</p> |