发明名称 TERT-BUTYLAMINE PRODUCTION PROCESS (VERSIONS)
摘要 FIELD: industrial organic synthesis. SUBSTANCE: method includes interaction of hydrocyanic acid with isobutylene in presence of water and acid catalyst at molar ratio of ingredients 1:1:1:(0.25-0.8), respectively. In another embodiment of invention, hydrocyanic acid interacts with isobutylene in presence of acid catalyst at molar ratio 1:1:(0.25-0.8). Acid catalyst is selected from the group including sulfuric, phosphoric, trifluoroacetic acids, sulfonic acids, and sulfonic acid cationites. Reaction mixture is held for 0.25 to 6 h at 20 to 60 C. Primarily obtained tert-butylformamide is subjected to alkali hydrolysis, while simultaneously distilling final product. EFFECT: improved feasibility and reproducibility of process. 4 cle
申请公布号 RU2114820(C1) 申请公布日期 1998.07.10
申请号 RU19970105137 申请日期 1997.04.10
申请人 OBSHCHESTVO S OGRANICHENNOJ OTVETSTVENNOST'JU "INK;OKHIM 发明人 GRISHINA B.S.;AFANAS'EV V.V.;KAZAKOV P.V.;TORUBAROV A.I.;STAROVOJTOV M.K.;KACHEGIN A.F.;RUDAKOVA T.V.;UVAROV K.A.;SERGEEV S.A.
分类号 C07C211/07;C07C209/62;(IPC1-7):C07C211/07 主分类号 C07C211/07
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