发明名称 N-(2-NITROBENZYLOXYCARBONYL) CYCLIC AMINES AND THEIR PRODUCTION
摘要 PROBLEM TO BE SOLVED: To obtain a new compound useful as a photobase-generating agent for photoresists, etc. SOLUTION: This compound is expressed by formula I [(m) is 5, 6; (n) is 0-2], e.g. NN-(2-nitrobenzyloxycarbonyl)pyrrolidine. The compound of formula I is obtained by reacting N,N'-carbonyldiimidazole with 2-nitrobenzyl alcohol and subsequently reacting the reaction product with a cyclic amine of formula II. The 2-nitrobenzyl alcohol and the cyclic amine of formula II are used in amounts of 0.95-1.0 mole and 1-1.5 moles, respectively, per mole of the N,N'- carbonyldiimidazole. Since the compound of formula I generates a secondary cyclic amine, is high in basicity and is small in nucleophilicity, the compound of formula I can give photoresists good in performances.
申请公布号 JPH1077264(A) 申请公布日期 1998.03.24
申请号 JP19960255501 申请日期 1996.09.05
申请人 SHIN ETSU CHEM CO LTD 发明人 YAGIHASHI FUJIO;KIYOMORI AYUMI;IWASAKI TOMOYUKI;HATAKEYAMA JUN
分类号 C07D295/20;C07D207/06;C07D211/16 主分类号 C07D295/20
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