Shunt recognition in lithium batteries

摘要

An apparatus and method of recognizing a shunt caused by formation of dendrites in a rechargeable lithium battery which comprises charging the battery with a charging current, sampling the charging current voltage of the battery at pre-determined time intervals in order to identify one or more point indicating onset of shunting, and terminating charging if the shunt or dendrite is indicated. If a shunt is not recognized charging is continued. Dendrite formation or the beginning of shunting due to such formation is indicated by any one of the following conditions: a negative gradient in sampled voltage values; a negative gradient in sampled steady open circuit values; and a negative gradient in the chemical polarization voltage values which may be calculated by sampling both the open circuit voltage soon after current interruption and steady open circuit voltages during a plurality of currentless phases.