Process for the preparation of crystalline vinylaromatic polymers with a predominant syndiotactic structure

摘要

Process for the preparation of crystalline vinylaromatic polymers with a predominant syndiotactic structure which involves polymerizing vinylaromatic monomers in the presence of a catalytic system comprising: a titanium complex having general formula (I): (I) wherein R1, R2, R3 and R4, the same or different, represent a hydrogen atom or a C1-C20 alkyl radical or a C6-C20 arylalkyl or aryl radical, on the condition that at least one of these is different from hydrogen.