发明名称 |
CATALYTIC HYDROGENOLYSIS OF ORGANIC THIOCYANATES AND DISULFIDES TO THIOLS |
摘要 |
A process for the preparation of a thiol comprising reacting hydrogen with a thiocyanate or disulfide wherein the reaction with thiocyanate is conducted in the presence of a catalyst comprising a Group VIII metal or a mixture thereof; and the reaction with thiocyanate or with disulfide is conducted in the presence of a catalyst comprising a Group VIII metal or mixture thereof in the presence of a modifier metal selected from a group consisting of Group IB, Group IIB, Group IIIA, Group IVA, Group VA and Group VIA metal or mixture thereof, said catalyst being on a porous insoluble support.
|
申请公布号 |
WO9737971(A1) |
申请公布日期 |
1997.10.16 |
申请号 |
WO1997US06014 |
申请日期 |
1997.04.04 |
申请人 |
E.I. DU PONT DE NEMOURS AND COMPANY |
发明人 |
JACOBSON, STEPHEN, ERNEST |
分类号 |
B01J23/44;B01J23/62;C07B61/00;C07C319/02;C07C319/06;C07C321/04;C07C321/10;C07C323/03;(IPC1-7):C07C319/06 |
主分类号 |
B01J23/44 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|