发明名称 ARIIRUKARUBONSANESUTERUNOSEIZOHOHOOYOBISORENIMOCHIIRUSHOKUBAI
摘要 PURPOSE: To produce the subject ester useful as the raw material for resin, etc., in high yield and selectivity on an industrial scale at a low cost by using a specific microporous material as a catalyst. CONSTITUTION: The objective ester of formula I [R<1> is a 1-10C alkyl, a 3-10C cycloalkyl or a 7-10C arylalkyl; R<2> is a (substituted) aryl] is obtained through the process of the ester interchange reaction of (B) an aliphatic carboxylic acid ester of formula II (R<3> is same as<1> ) with (C) a hydroxy compound of formula III in the presence of (A) a heterogeneous catalyst consisting of a microporous material containing a group IV metal element in a liquid phase. Further, metallosilicate (crystalline titanosilicate), metalloaluminosilicate or metal loaluminophosphate (crystalline titanoaluminophosphate) is preferably used in the component A.
申请公布号 JP2659174(B2) 申请公布日期 1997.09.30
申请号 JP19950011054 申请日期 1995.01.26
申请人 NIPPON SHOKUBAI KK 发明人 TSUNEKI HIDEAKI;WATANABE KENICHI;ONDA YOSHUKI
分类号 B01J29/83;B01J21/16;B01J29/84;B01J29/89;C07B61/00;C07C67/02;C07C69/035;C07C69/155;C07C69/157;C07C69/24;C07C69/612;C07C69/74 主分类号 B01J29/83
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