发明名称 Electrolytes for inhibiting silver deposition on oxygen sensor cathodes and methods of use of same
摘要 A Clark-type gas detection apparatus includes a sensor electrode and a reference electrode exposed to an aqueous electrolyte solution which is isolated from a liquid medium surrounding the apparatus by a semi-permeable membrane. A preferred reference electrode for use in Clark-type apparatus comprises silver/silver chloride. Through the addition of an effective amount of a sulphate-based co-electrolyte to an electrolyte solution having a relatively low chloride ion content, it is possible to obtain an electrolyte solution having an ionic conductivity comparable to that of chloride-based electrolyte solutions currently used in Clark-type sensors while retaining sufficient chloride ion to drive the oxidation reaction near the reference electrode. The relatively low chloride ion content of the electrolyte solution of the present invention tends to suppress the dissolution of silver chloride from the reference electrode, and, consequently, the deposition of silver on the indicating electrode.
申请公布号 US5632882(A) 申请公布日期 1997.05.27
申请号 US19960681657 申请日期 1996.07.29
申请人 YSI INCORPORATED 发明人 WU, HUAN P.
分类号 G01N27/49;(IPC1-7):G01N27/404 主分类号 G01N27/49
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