| 摘要 |
Additives for lubricating oils, hydrocarbon oils and power transmitting fluids are oil-soluble esters of hydrocarbon substituted succinic acid, the hydrocarbon being saturated and being a polymer containing at least 50 aliphatic carbon atoms. Examples of the ester are the dimethyl ester of polyisobutene succinic anhydride, the polyisobutene succinic anhydride which has been esterified with polyethylene glycol and further reacted with barium oxide to produce a mixed ester-metal salt and the polyisobutene succinic anhydride which has been esterified with a styrene-allyl alcohol copolymer and then reacted with propylene oxide. Examples are given of the addition of these esters to SAE mineral lubricating oils which may also include the usual additives especially the metal phosphor dithioates and their epoxide adducts.ALSO:The invention comprises an oil-soluble ester of a hydrocarbon-substituted succinic acid, the hydrocarbon being saturated and being a polymer containing at least 50 aliphatic carbon atoms. The ester may be prepared by reacting an alcohol or phenol with a hydrocarbon-substituted succinic anhydride or acid, preferably at 150 DEG to 300 DEG C. and in the presence of an esterification catalyst, by reacting an epoxide or a mixture of an epoxide and water with a hydrocarbon substituted succinic anhydride or acid or acid halide, by reacting maleic acid or anhydride with an alcohol and reacting the obtained mono- or di-ester of maleic acid with the polyolefin, and, finally by esterifying itaconic anhydride or acid and then reacting with the polyolefin. The preferred method is by reacting a polyhydric alcohol having 2-10 OH radicals with 0.5-10 moles of hydrocarbon-substituted succinic anhydride, the hydrocarbon being a polymer of a C2- 6 mono-olefin having a M.Wt. of 700-5000. The examples relate to the treatment of polyisobutene succinic anhydride and of the succinic anhydride of the copolymer of 90 isobutene and 10 piperylene. The esters may be used as lubricant addititives. |
