| 摘要 |
Compositions comprising water, microbicidally active 3-isothiazolone compound, and an effective stabilizing amount of unsaturated, cyclic iodosyl or iodyl compound of formula I and II <IMAGE> (I) (O); Y=O, NR3; R1=H, Cl, Br, I, substituted or unsubstituted C1-C18 alkyl, substituted or unsubstituted C2-C18 alkenyl, substituted or unsubstituted C4-C6 aryl, substituted or unsubstituted C7-C10 aralkyl; R2=H, Cl, Br, I, substituted or unsubstituted C1-C18 alkyl, substituted or unsubstituted C2-C18 alkenyl, substituted or unsubstituted C4-C6 aryl, substituted or unsubstituted C7-C10 aralkyl, SO3H, CO2R4, C(O)NR5R6; R1 and R2 may by joined to form a substituted or unsubstituted 5 or 6 membered ring, optionally fused to another 5 or 6 membered aromatic ring; R3=H, C(O)R7, substituted or unsubstituted C1-C18 alkyl, substituted or unsubstituted C2-C18 alkenyl, substituted or unsubstituted C4-C6 aryl, substituted or unsubstituted C7-C10 aralkyl; R4=H, substituted or unsubstituted C1-C18 alkyl, substituted or unsubstituted C2-C18 alkenyl, substituted or unsubstituted C4-C6 aryl, substituted or unsubstituted C7-C10 aralkyl, (CH2CH2)p-OH, M; R5=H, substituted or unsubstituted C1-C18 alkyl, CH2CH2SO3H, CH2CH2SO3M; R6=H, substituted or unsubstituted C1-C18 alkyl; R7=H, substituted or unsubstituted C1-C18 alkyl, substituted or unsubstituted C2-C18 alkenyl, substituted or unsubstituted C4-C6 aryl, substituted or unsubstituted C7-C10 aralkyl; R8, R9, R10 are independently selected from the group consisting of CN, OH, C1-C4 alkyl, C1-C4 alkoxy, Cl, Br, F, NO2, SO3H, SO3M, OCH2CH2N+R63 X-, CO2H, CO2M, OPO3H; M=a monovalent or divalent metal cation; X=halogen; n=0, 1; and p=1-30, are disclosed. Also disclosed are methods of stabilizing a microbicidally active 3-isothiazolone in a water solution comprising introducing an effective stabilizing amount of unsaturated, cyclic iodosyl or iodyl compound of formula I and II.
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