摘要 |
<p>A polymerization initiator composition controlling polymerization at interface, comprising a (thio)barbituric acid compound represented by the general formula I: <CHEM> wherein R<1> is an alkyl group of 1 to 3 carbon atoms, R<2> and R<3> are independently hydrogen atom or an alkyl group of 1 to 3 carbon atoms, and X is oxygen atom or sulfur atom, and (a) a metal halide represented by the general formula, MYn wherein M is Cu or Fe, Y is halogen atom, and n is an integer of 2 when M is Cu or an integer of 3 when M is Fe, or (b) a halogen ion-forming compound and M<m>-forming compound wherein M is Cu or Fe and m is 2+ when M is Cu or 3+ when M is Fe, and a curable composition comprising the (thio) barbituric acid and radically polymerizable monomer.</p> |