发明名称 PRODUCTION OF TRANS-DIFLUOROETHYLENE DERIVATIVE
摘要 PURPOSE: To readily and economically obtain a trans-difluoroethylene derivative useful as a liquid crystal compound in high yield and by a short process by reacting a specific trifluoroethylene compound with a Li compound. CONSTITUTION: This compound of formula III is obtained by reacting (A) a compound of formula I [R<2> is an (F-substituted) 1-10C alkyl, a halogen or CN; A<4> is a (CN-substituted) 1,4-disubstituted cyclohexylene or a 1,4-disubstituted cyclohexenylene; Y<2> is COO, C≡C or CH2 CH2 ; A<3> is a (CN-substituted) 1,4- disubstituted cyclohexenylene or 1,4-disubstituted phenylene; (n) is 0 or 1] with a compound of formula II [R<1> is R<2> ; A<1> is A<4> ; Y<1> is Y<2> ; A<2> is a (CN-substituted) trans-1,4-disubstituted cyclohexylene; (m) is (n)].
申请公布号 JPH08119887(A) 申请公布日期 1996.05.14
申请号 JP19940252539 申请日期 1994.10.18
申请人 ASAHI GLASS CO LTD 发明人 SHIMIZU TAMAKI;YOKOKOJI OSAMU;KUMAI SEISAKU
分类号 G02F1/13;C07C17/263;C07C22/00;C07C22/08;C07C25/24;C07C35/50;C07C39/42;C07C43/192;C07C43/225;C07C69/62;C07C69/66;C07C69/75;C07C69/753;C07C69/76;C07C69/773;C07C69/86;C07C69/92;C07C255/50;C07D211/14;C07D211/18;C07D211/38;C07D211/40;C07D239/26;C07D239/34;C07D319/06;C09K19/16;C09K19/18;C09K19/20;C09K19/30;C09K19/34;(IPC1-7):C07C22/00 主分类号 G02F1/13
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