Process for the production of carbon molecular sieves

摘要

PCT No. PCT/EP92/02275 Sec. 371 Date Mar. 21, 1994 Sec. 102(e) Date Mar. 21, 1994 PCT Filed Oct. 1, 1992 PCT Pub. No. WO93/06920 PCT Pub. Date Apr. 15, 1993.A process is disclosed for preparing a carbon molecular sieve used for the separation of oxygen from nitrogen, which comprises the steps of: (a) milling hard coal to a grain size of 95%<20 mu m; (b) oxidizing the finely milled hard coal with air in a fluidized bed; (c) adding water and coal tar pitch as a binder and molding the finely milled hard coal into shape; (d) carbonizing the finely milled hard coal molded into shape in a rotary kiln at a temperature of 500 DEG to 850 DEG C., with a dwelling time of 55 to 65 minutes, in order to obtain a carbonization product with a bulk density of 530 to 560 g/l; (e) activating the carbonization product with steam at to 900 DEG C. for 165 to 195 minutes to obtain a sintered carbonaceous product having a bulk density of 590 to 650 g/l; and (f) treating the sintered carbonaceous product at 750 to 850 DEG C. with carbon-splitting hydrocarbons to obtain said carbon molecular sieve.