发明名称 Suporte para facricação de catalisador de acetato de vinila processos para fabricação de suporte inerte para catalisador de acetato de vinila para feito fluido para fabricação de catalisador de acetato de vinila para leito fluido catalisador de acetato de vinila para leito fluido e processo para produção de acetato de vinila
摘要 <p>A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm<3>/g and the surface area is from 100 to 200 m<2>/g.</p>
申请公布号 BR9500736(A) 申请公布日期 1995.10.31
申请号 BR19959500736 申请日期 1995.02.22
申请人 THE STANDARD OIL COMPANY 发明人 PATRICIA RAE BLUM;LARRY MICHAEL CIRJAK;MICHAEL FRANCIS LEMANSKI;CHRISTOS PAPERIZOS;MARC ANTHONY PEPERA;DEVASIRVATHAM DHANARAH SURESH
分类号 B01J21/08;B01J23/44;B01J23/52;B01J23/56;B01J23/58;B01J23/60;B01J23/62;B01J23/63;B01J23/644;B01J23/648;B01J23/66;B01J23/68;B01J32/00;B01J35/10;B01J37/00;B01J37/02;B01J37/04;C07B61/00;C07C67/04;C07C67/055;C07C69/15;(IPC1-7):C08F18/08 主分类号 B01J21/08
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