| 摘要 |
A process of preparing diaryl carbonates, such as diphenyl carbonate, and aryl haloformates, such as phenyl chloroformate. The process involves contacting phenol or a substituted phenol with a carbonyl halide, such as phosgene, in the presence of a phosphorus-containing catalyst. The catalyst is selected from alkyl phosphates, aryl phosphites, aryl phosphates, organic phosphinites and phosphinates, organic pyrophosphates, inorganic phosphorous and phosphoric acids, and phosphorus oxides. |
