发明名称 |
ELECTROCHEMICAL GENERATION OF N-O |
摘要 |
A process is provided for the electrochemical generation of N2O5 in HNO3, whereby a solution of N2O4 in HNO3 is electrolysed. An electrolytic cell for the electrolysis is also provided, having substantially parallel electrodes in electrode compartments separated by a cell membrane. The anode is of Pt, Nb, Nb/Ta 40:60 alloy with a Pt coating. The cathode is Pt, stainless steel, Nb, Nb/Ta 40:60 alloy. The cell membrane is preferably a perfluorinated cationic exchange membrane. In use N2O5 forms in the anolyte and N2O4 increases in the catholyte. A suitable design of cell and its use in a single- or multistage electrolysis process is also described.
|
申请公布号 |
CA1335885(C) |
申请公布日期 |
1995.06.13 |
申请号 |
CA19880569722 |
申请日期 |
1988.06.17 |
申请人 |
SECRETARY OF STATE FOR DEFENCE IN HER BRITANNIC MAJESTY'S GOVERNMENT OF THE UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND (THE) |
发明人 |
MARSHALL, RODNEY J.;SCHIFFRIN, DAVID J.;WALSH, FRANCIS C.;BAGG, GREVILLE E. G. |
分类号 |
C25B1/30;C25B1/00;(IPC1-7):C25B1/00 |
主分类号 |
C25B1/30 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|