发明名称 |
Process for Preparing Carboxylic Acids or Corresponding Esters Using an Iridium-Based Catalyst |
摘要 |
The present invention relates to the preparation of carboxylic acids or of the corresponding esters by reaction of an alcohol with carbon monoxide in the presence of a catalyst containing iridium and of a halogenated promoter. The reaction is carried out with a reaction mixture whose composition is maintained throughout the operation. The said mixture comprises between 0 exclusive and 10% of water, between 0 exclusive and 10% of halogenated promoter, and between 2 and 40% of ester corresponding to the reaction of the abovementioned carboxylic acid and alcohol, the said carboxylic acid constituting the solvent of the reaction. |
申请公布号 |
CA2120287(A1) |
申请公布日期 |
1994.10.01 |
申请号 |
CA19942120287 |
申请日期 |
1994.03.30 |
申请人 |
RHONE-POULENC CHIMIE |
发明人 |
NOBEL, DOMINIQUE;PERRON, ROBERT |
分类号 |
B01J23/46;B01J27/13;B01J31/20;C07B61/00;C07C45/50;C07C51/12;C07C53/08;C07C53/122;C07C53/124;C07C53/126;C07C67/36;C07C69/14;(IPC1-7):C07C53/00;C07C67/37 |
主分类号 |
B01J23/46 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|