发明名称 |
Method of preparation of 1,2- and 1,3- propanediol. |
摘要 |
The invention relates to a method for the simultaneous preparation of 1,2- and 1,3-propanediol from glycerol. 1,2-Propanediol is customarily prepared from propylene oxide, 1,3-propanediol by hydration of acrolein with subsequent hydrogenation. The process according to the invention comprises the reaction stages (a) dehydration of glycerol by passing a gaseous glycerol/water mixture containing 10 to 40% by weight of glycerol at 250 to 340@C over a solid catalyst having an Ho value (Hammett's acid function) of less than 2, preferably between -3 and -8.2, (b) hydration of the acrolein contained in the reaction mixture of stage (a) and (c) catalytic hydrogenation of the reaction mixture containing the 3-hydroxypropionaldehyde and hydroxyacetone of stage (b). Two useful substances, namely 1,2- and 1,3-propanediol, can simultaneously be obtained in a high total yield from glycerol in a simple process. |
申请公布号 |
EP0598228(A1) |
申请公布日期 |
1994.05.25 |
申请号 |
EP19930116791 |
申请日期 |
1993.10.18 |
申请人 |
DEGUSSA AKTIENGESELLSCHAFT |
发明人 |
HAAS, THOMAS,DR.;NEHER, ARMIN, DR.;ARNTZ, DIETRICH, DR.;KLENK, HERBERT, DR.;GIRKE, WALTER |
分类号 |
C07C31/20;C07C29/136;C07C29/141;C07C29/145;C07C45/52;C07C45/64;C07C47/22;C07C49/17 |
主分类号 |
C07C31/20 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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