发明名称 |
Production of organosilanes from polysilanes. |
摘要 |
<p>The present invention is a process for the production of organosilanes from the high-boiling residue resulting from the reaction of organohalides with silicon metalloid in a process typically referred to as the "direct process." The present process comprises forming a mixture comprising a organotrihalosilane and the high-boiling residue in the presence of hydrogen gas, a hydrogenolysis catalyst and a redistribution catalyst. The organotrihalosilane and high-boiling residue are converted into commercially useful di- and triorganosilanes and organohydrosilanes. The present process results in consumption of the organotrihalosilane rather than the net increase which typically occurs in the absence of the redistribution catalyst.</p> |
申请公布号 |
EP0564109(A1) |
申请公布日期 |
1993.10.06 |
申请号 |
EP19930301803 |
申请日期 |
1993.03.10 |
申请人 |
DOW CORNING CORPORATION |
发明人 |
BOKERMAN, GARY NED;CANNADY, JOHN PATRICK;OGILVY, ANN ELIZABETH |
分类号 |
B01J21/12;B01J23/42;B01J23/44;B01J23/755;C07B61/00;C07F7/12 |
主分类号 |
B01J21/12 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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