Removal of carbonyl impurities from a carbonylation process stream.

摘要

The methyl iodide recycle stream to a carbonylation reactor for carbonylating methanol or methyl acetate to acetic acid, acetic anhydride or both is treated to remove carbonyl impurities by reacting the methyl iodide stream with an aqueous amino compound which reacts with the carbonyls to form water soluble nitrogenous derivatives, separating an organic methyl iodide phase from an aqueous derivative phase and distilling the methyl iodide phase to remove heavier impurities. The treatment of the methyl iodide recycle stream to the carbonylation reactor has been found to greatly reduce the carbonyls present in the product acetic acid or acetic anhydride and reduce tar formation in acetic anhydride and acetic acid-acetic anhydride co-production units. The formation of nitrile from the nitrogenous derivative during distillation is minimized by adding water to the distillation column which washes the nitrogenous derivatives from the methyl iodide overhead.