| 发明名称 |
ELEKTROLEITFAEHIGE, MIT HETEROPOLYANIONEN DOTIERTE LEITER, VERFAHREN ZUR HERSTELLUNG UND IHRE ANWENDUNG BEI DER CHEMISCHEN UND ELEKTROCHEMISCHEN KATALYSE. |
| 摘要 |
An electronically conductive polymer doped with anions of a heteropolyacid of formula: Hn(XMyVy',Oz> in which n, y, y' and z are such that 2</=n</=6, 6</=y</=18, 0</=y'</=12, 24</=z</=70 and 6</=y+y'</=18, X is an element such as P or Si, and M is Mo or W. These polymers can be prepared by chemical or electrochemical oxidation from a solution containing the heteropolyacid and the monomer capable of forming an electronically conductive polymer by oxidation, for example pyrrole, thiophene, aniline, para- phenylenediamine, acetylene, benzene and their substituted derivatives. The doped electronically conductive polymer obtained can reduce the protons of a solution as shown by the curve (1) of enclosed Figure 2. <IMAGE> |
| 申请公布号 |
DE3875333(T2) |
申请公布日期 |
1993.04.22 |
| 申请号 |
DE19883875333T |
申请日期 |
1988.12.27 |
| 申请人 |
COMMISSARIAT A L'ENERGIE ATOMIQUE ETABLISSEMENT DE CARACTERE SCIENTIFIQUE TECHNIQUE ET INDUSTRIEL, PARIS, FR |
发明人 |
BIDAN, GERARD, F-38100 GRENOBLE, FR;GENIES, EUGENE, F-38120 SAINT EGREVE, FR;LAPROWSKI, MIETTCZYSLAW, ZABZE, PL |
| 分类号 |
B01J31/34;B01J27/188;B01J27/19;B01J31/06;B01J35/00;C07B61/00;C08G61/12;C08K3/22;C08L65/02;C08L101/00;C25B11/00;H01B1/12;H01M4/60;H01M4/90 |
主分类号 |
B01J31/34 |
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