发明名称 |
Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide |
摘要 |
A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media. |
申请公布号 |
US5198589(A) |
申请公布日期 |
1993.03.30 |
申请号 |
US19920874897 |
申请日期 |
1992.04.28 |
申请人 |
THE UNITED STATES OF AMERICA AS REPRESENTED BY THE UNITED STATES DEPARTMENT OF ENERGY |
发明人 |
RATHKE, JEROME W.;KLINGLER, ROBERT J. |
分类号 |
C07C45/50 |
主分类号 |
C07C45/50 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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