发明名称 Process for producing alpha -olefin polymers
摘要 A process for producing an alpha -olefin polymer which comprises homopolymerizing or copolymerizing an alpha -olefin by the use of a catalyst system comprising: (A) a solid catalyst component (A) containing at least magnesium, titanium, halogen and ester compound as indispensable components, and (B) a catalyst component (B) produced by reacting an organoaluminum compound represented by general formula R1mAlY3-m (R1 represents an aliphatic hydrocarbon group having 1 to 8 carbon atoms, Y represents halogen, hydrogen or alkoxy group having 1 to 20 carbon atoms, and m represents a number satisfying 2</=m</=3) with an organic silicon compound represented by general formula R2nSi(OR3)4-n (R2 represents alicyclic hydrocarbon group or aromatic hydrocarbon group having 5 to 20 carbon atoms, R3 represents a hydrocarbon group having 1 to 20 carbon atoms, and n represents a number satisfying 0</=n</=3) in the state of a solution so that the product of this reaction becomes satisfying the following formula: 0.2</=K</=2.2, wherein: <IMAGE> [S represents the area of a peak in 13C-NMR spectrum of the reaction product assignable to Al-R1 bond, S' represents the area of a peak in 13C-NMR of the product assignable to the Si-R1 bond formed by the reaction with organoaluminum compound, and Z represents molar ratio of Si atom to Al atom in component (B)].
申请公布号 US5189124(A) 申请公布日期 1993.02.23
申请号 US19910801584 申请日期 1991.12.05
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 SASAKI, TOSHIO;EBARA, TAKESHI;JYOHOJI, HIROFUMI;MIZUNUMA, KOOJI;KAWAI, KIYOSHI
分类号 C08F10/00 主分类号 C08F10/00
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