发明名称 SPHERICAL PARTICLE OF CROSS-LINKED GLUCOMANNAN, PREPARATION THEREOF, AND ION EXCHANGER
摘要 PURPOSE:To prepare the title particles having micropores with sufficient diameters and a sufficient compressive strength by saponifying and cross-linking spherical particles obtd. by evaporating a solvent for liq. droplets formed by suspending a low-boiling-solvent soln. of a low-mol. -wt. glucomannan ester contg. a foaming agent in an aq. medium. CONSTITUTION:A low-mol. -wt. glucomannan ester obtd. by esterifying low-mol.- wt. glucomannan or by lowering the mol.wt. of glucomannan while esterifying it and a foaming agent are dissolved in a solvent which has a b.p. lower than that of an aq. medium and which is insoluble or hardly soluble in the aq. medium, thereby giving a stock solution. The soln. is suspended in the aq. medium to form liq. droplets, from which the solvent is removed by evaporation, giving spherical particles of the low-mol.wt. glucomannan. The particles are saponified and reacted with a cross-linker to give the title particles having a mean micropore size of 0.5-10mum. Thus are obtd. spherical particles having micropores through which a substance having a size of the order of mum can permeate and having a practically sufficient compressive strength.
申请公布号 JPH04180936(A) 申请公布日期 1992.06.29
申请号 JP19900308118 申请日期 1990.11.14
申请人 KURITA WATER IND LTD 发明人 MORITA HIROSHI
分类号 B01J20/281;B01J20/24;B01J41/16;B01J45/00;C08B37/00;C08J3/12;C08J3/24;C08L5/00;G01N30/88 主分类号 B01J20/281
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