| 摘要 |
Polyamide-esters may produce by reacting a polyethylene glycol monoamine with one or more dicarboxylic acids. Two methods may be employed: (1) the polyethylene glycol monoamine may be reacted with at least two different dicarboxylic acids simultaneously, or (2) the polyethylene glycol monoamine may be reacted with a first dicarboxylic acid in a first step to form an adduct, and then reacting the adduct with a second dicarboxylic acid to form the polyamide-esters, where the first and second dicarboxylic acids may be the same or different. Suitable dicarboxylic acids include, adipic acid; terephthalic acid; isophthalic acid; t-butyl isophthalic acid; 1,1,3-trimethyl-5-carboxy-3-(p-carboxyphenyl) indane, also known as phenylindane dicarboxylic acid (PIDA); naphthalenic dicarboxylic acid and mixtures thereof. Suitable polyethylene glycol monoamines include diethylene glycol monoamine, triethylene glycol monoamine and tetraethylene glycol monoamine. Terephthalic acid is a preferred acid, and in one embodiment gives polyamide-esters with the formula <IMAGE> +TR <IMAGE> where R is an alkyl or aryl group having from 3 to 34 carbon atoms, x ranges from 2 to 6, and y ranges from about 2 to about 50.
|
