摘要 |
Prodn. of butanedicarboxylic acid methyl esters (I) is effected by reacting a methyl pentenoate (II) with CO and MeOH in the presence of pyridine and/or picolines (III) and a Co catalyst at elevated temp. and pressure, and treating the reaction mixt. with an O2-contg. gas and aq. HOAc. (III) are recovered by (a) sepg. the reaction mixt. into an aq. phase contg. Co(OAc)2, (III), HOAc and MeOH, and an organic phase contg. (I), by-products, (II), HOAc and (III); (b) extracting (III) from the organic phase with aq. HOAc; (c) combining the extract with the aq. phase; and (d) distilling (III) from the mixt. to leave an aq. soln. contg. Co(OAc)2 and HOAc.
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申请人 |
BASF AG, 6700 LUDWIGSHAFEN, DE |
发明人 |
LENDLE, DR., HUBERT, W-6700 LUDWIGSHAFEN, DE;PANITZ, PAUL, W-6520 WORMS 1, DE;SEYFERT, DR., WILFRIED, W-6719 WEISENHEIM, DE;STOPS, PETER, W-6701 ALTRIP, DE |