UMWANDLUNG VON C3- UND C4-KOHLENWASSERSTOFFEN IN WENIGER GESAETTIGTE KOHLENWASSERSTOFFE.

摘要

A method for the conversion of C3 and C4 hydrocarbons to less saturated hydrocarbons, such as ethylene and propylene and particularly ethylene, includes contacting the feed hydrocarbons with mixed oxides comprising a major proportion of magnesium and a minor proportion of manganese, preferably under conditions which selectively convert the feed hydrocarbons to ethylene and ethane and particularly ethylene, including a temperature between about 625 DEG C. and 850 DEG C. The method is preferably carried out in the presence of steam at a mole ratio of steam/hydrocarbon of less than about 10:1. Selectivity to ethylene and ethane and particularly ethylene is improved and the life of the catalyst, during which the desired selectivity is attained, is extended by adding a promoting amount of at least one oxide of calcium, barium, strontium, tin and antimony. Further improvement can be obtained by limiting the amount of bound or fixed sulfur in the catalyst.