发明名称 VERFAHREN ZUM HYDRIEREN
摘要 The invention relates to a process for hydrogenating native fats, oils and fatty derivatives like fatty acids and fatty acid esters to form fatty alcohols in fixed-bed reactors, especially with constant flow, in which hydrogen is passed through the circuit in stoichiometric excess, especially to the extent of 10 to 100-fold and the fat, oil or fatty derivative passes through the reactor only once. To reduce the specific hydrogen consumption without substantial penalties relating to the specific reactor load, product selectivity and catalyst life, it is proposed that the hydrogen is taken through at least two fixed-bed reactors (4, 10) in succession without allowing the gas leaving the reactors (4), and entering the subsequent reactors (10) to cool and that the fat, oil or fatty derivative is fed in parallel into the reactors (4, 10).
申请公布号 DE4005629(A1) 申请公布日期 1991.08.29
申请号 DE19904005629 申请日期 1990.02.22
申请人 HENKEL KGAA, 4000 DUESSELDORF, DE 发明人 CARDUCK, FRANZ-JOSEF, DR., 5657 HAAN, DE;GOEBEL, GERD, DR., 5000 KOELN, DE;FLECKENSTEIN, THEO, DR., 4010 HILDEN, DE;KREUTZER, UDO, DR., 4019 MONHEIM, DE;DEMMERING, GUENTHER, DR., 5650 SOLINGEN, DE
分类号 B01J23/86;C07B61/00;C07C29/149;C07C31/04;C07C31/125;C07C31/20;C11C1/02;C11C3/12 主分类号 B01J23/86
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