发明名称 PRODUCTION OF STYRENE-BASED POLYMER
摘要 PURPOSE:To efficiently obtain the subject polymer excellent in heat resistance and moldability and having a high rate of crystallization by using a specified catalyst in polymerization of a styrene-based monomer and an indene-based monomer. CONSTITUTION:Using (A) a transition metal component (preferably cyclopentadienyl titanium trimethoxide, etc.) and (B) a product compound (preferably methylaluminoxane which is product compound of catalytic reaction between trimethylaluminum and water) of a catalytic reaction between an organoaluminum compound and a condensation agent as catalyst components, a styrene-based monomer (e.g. styrene) of formula I (R<1> is H, halogen, etc.; m is 1-3) and an indene-based monomer (e.g. 1-methylindene) of formula II (R<2>-R<5> are R<1>; n is 1-4) are polymerized to obtain the objective polymer. In addition, the reaction is preferably carried out at 10-70 deg.C and for 1hr or more.
申请公布号 JPH03166203(A) 申请公布日期 1991.07.18
申请号 JP19890307871 申请日期 1989.11.24
申请人 IDEMITSU KOSAN CO LTD 发明人 WATANABE MASAMI;MACHIDA SHUJI;ASAHI SATOSHI
分类号 C08F12/00;C08F4/642;C08F4/659;C08F4/6592;C08F12/04;C08F12/14;C08F30/04;C08F212/00;C08F212/06;C08F230/00;C08F232/08 主分类号 C08F12/00
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