BILAYER OXIDE FILM AND PROCESS FOR PRODUCING SAME

摘要

A bilayer oxide film (13) which comprises a preferably porous layer containing aluminum oxide (13A) and a non-porous layer comprising an oxide of a valve metal (13B), e.g. tantalum. The layers are integral. The film is produced by forming a coating (12) of aluminum or an anodizable aluminum alloy on a valve metal (or alloy) (11), anodizing the resulting structure in an electrolyte (preferably one capable of converting the aluminum (or alloy) to a porous oxide film) in the presence of an adhesion-reducing agent (e.g. fluoride ions) that makes the resulting anodized bilayer film (13) easily detachable from the remaining valve metal (11). The bilayer film (13) is then detached from the valve metal (11), e.g. by adhering a flexible plastic film (14) to the bilayer and using the film to peel off the bilayer from the valve metal (11). The resulting bilayer (13) can be used for a variety of purposes, e.g. as a vapour or oxygen barrier, or as a coating containing magnetic particles (16) used to make a magnetic recording medium.