| 摘要 |
<p>A process for producing a highly-orientated ultralong conjugated polymer while the orientation thereof is maintained, which comprises: a step of immersing a substrate having a hydrophilic surface in a nonaqueous organic solvent containing a compound having at least an unsaturated group, such as an acetylenic group, etc., and -SiAxH3-x group in which A denotes chloro or lower alkyl and x is an integer of from 1 to 3, whereby forming a monomolecular film of the above compound on the substrate, a step of orientation the monomolecular film in a specific direction, and a step of polymerizing the monomolecular film by using irradiation or a metal salt catalyst, the irradiation using electron beam, X-ray or gamma ray, the metal salt catalyst being MoCl5, MCl6, NbCl5, TaCl5, or the like as a metal halide catalyst, or Mo(CO)5, W(CO)6, Nb(CO)5, Ta(CO)5, or the like as a metal carbonyl catalyst.</p> |
