摘要 |
PURPOSE:To allow bleach-fixing in a short period of time without generating recoloration defects by processing the silver halide color photographic sensitive material contg. cyan couplers by a bleach-fix bath contg. the ferric complex salts of specific compds. CONSTITUTION:The photosensitive material contg. at least one of the cyan couplers expressed by formula I, etc., is processed by the bleach-fix bath contg. at least one of the ferric complex salts of the compds. expressed by formula II, etc., and contg. at least 1.0mol/l thiosulfate, In formula I, R1 denotes an alkyl group, alkenyl group, etc.; Y denotes -CONHCOR2, -CONHSO2R2, etc., 2 denotes a hydrogen atom or a group which can be eliminated by coupling reaction with the oxidant of an arom. primary amine color developing agent; in formula II, A1 to A4 denote -CH2OH, -COOM, etc., which may be respectively the same or different; M, M1, M2 respectively denote a hydrogen atom, sodium, etc.; X denotes 3 to 6C substd. or unsubstd. alkylene group. The generation of cyan stains, a desilvering property and the formation of leuco pigment are obviated in this way and the rapid processing is possible. |