发明名称 CATALYTIC OXIDATION WITH N-HYDROXYDICARBOXYLIC ACID IMIDES
摘要 1. A process for the catalytic oxidation of allylic groups with oxygen or an oxygen-containing gas, characterized by oxidizing an isoprenoid, which has at least one allylic hydrogen atom, in an inert ketone or ester in the presence of a N-hydroxydicarboxylic acid imide of the general formula see diagramm : EP0198351,P8,F2 wherein A-B stands for CH2 -CH2 , CH=CH, an aromatic hydrocarbon residue or a group derived from one of these groups in which one or more hydrogen atoms is/are replaced by alkyl or halogen, and, if desired, reducing a hydroperoxide obtained to the alcohol or dehydrating a primary or secondary hydroperoxide obtained to the carbonyl compound.
申请公布号 DE3666417(D1) 申请公布日期 1989.11.23
申请号 DE19863666417 申请日期 1986.04.04
申请人 F. HOFFMANN-LA ROCHE AG 发明人 FORICHER, JOSEPH;FURBRINGER, CLAUDE;PFOERTNER, KARLHEINZ, DR.
分类号 C07D207/46;B01J31/00;B01J31/02;C07B31/00;C07B41/02;C07B41/06;C07B61/00;C07C27/00;C07C29/132;C07C29/48;C07C33/02;C07C45/00;C07C45/34;C07C45/53;C07C49/453;C07C49/603;C07C49/627;C07C49/653;C07C67/00;C07C407/00;C07C409/04;C07C409/14;C07D209/48;C07D209/66;C07J9/00 主分类号 C07D207/46
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