发明名称 PROCESS FOR THE PREPARATION OF GLYCIDYL THIOETHERS
摘要 1. A process for producing glycidyl thioethers of the formula I see diagramm : EP0166695,P6,F3 by reacting equimolar amounts of epichlorohydrin with a mercaptan of the formula II R-SH (II) wherein R is a radical see diagramm : EP0166695,P6,F5 in which R**1 , R**2 and R**3 independently of one another are each C1 -C18 alkyl and together have no more than 22 C atoms, and R**2 and R**3 are in addition hydrogen, or wherein R is C5 -C6 cycloalkyl, phenyl or naphthyl unsubstituted or substituted by C1 -C4 alkyl, or is benzyl or furfuryl, or wherein R is mercaptoalkyl which has 2 to 8 C atoms and can be interrupted by 1 or 2 ether-O atoms, and wherein the reaction is carried out at a temperature of -30 degrees C to +20 degrees C without organic solvent and in the presence of a base, by the phase-transfer catalysis process, in contact with an aqueous phase, a phase-transfer catalyst being employed.
申请公布号 EP0166695(B1) 申请公布日期 1989.10.18
申请号 EP19850810291 申请日期 1985.06.24
申请人 CIBA-GEIGY AG 发明人 WIRTH, HERMANN O., DR.;FRIEDRICH, HANS-HELMUT
分类号 B01J31/02;C07B61/00;C07D207/26;C07D207/27;C07D213/70;C07D215/36;C07D277/36;C07D277/74;C07D285/12;C07D285/125;C07D301/27;C07D303/34;C10M135/24;C10M135/26;C10M135/28;C10M135/32;C10M137/10 主分类号 B01J31/02
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