| 摘要 |
PROCESS FOR THE PREPARATION OF AN AROMATIC HYDROCARBON MIXTURE The invention relates to a process for the preparation of an aromatic hydrocarbon mixture, wherein one or more monoolefins with two to four carbon atoms per molecule or aliphatic hydrocarbons, at least 50 %wt of which consisting of the said olefins, are contacted at a temperature of between 325 and 700 .degree.C with a catalyst containing a crystalline gallium silicate, which silicate has the following distinguishing features after calcination for one hour in air at 500 .degree.C: a) an X-ray powder diffraction pattern that contains as strongest lines the four lines listed in Table A, and, b) in the formula which gives the composition of the silicate expressed in moles of the oxides, the SiO2/Ga2O3 mol. ratio is between 25 and 250, and wherein, if the silicate has a SiO2/Ga2O3 mol. ratio of 100-250, the catalyst is subjected to a two-stage treatment comprising a first stage in which the catalyst is contacted for at least 15 minutes at a temperature of 350-700 .degree.C with a hydrogen-containing reducing gas, followed by a second stage in which the catalyst is contacted for at least 15 minutes at a temperature of 350-700 .degree.C with an oxygen-containing oxidizing gas. The relation between the C5+ content and the aromatics content in the hydrocarbon mixture obtained is improved. |
