发明名称 PREPARATION OF METHYL AND ETHYL ESTERS OF CYCLOPROPANE CARBOXYLIC ACIDS
摘要 Compounds of the general formula <IMAGE> in which R<1> and R<2> in each case stand for an alkyl group having 1 to 4 carbon atoms or together form an alkylene group having up to 5 carbon atoms, X<1> and X<2> in each case stand for a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or for a halogen atom or, with one another, form an alkylene group having up to 5 carbon atoms or X<1> denotes a hydrogen atom and X<2> is a monohalovinyl, dihalovinyl or dimethylvinyl group and R stands for a methyl or ethyl group, are prepared. A procedure is used in which a cyclopropanenitrile of the general formula <IMAGE> is reacted with methanol or ethanol under substantially anhydrous conditions at a temperature from 80 to 200 DEG C and in the presence of a mineral acid as a reaction catalyst and of a scavenging agent for the ammonia formed during the reaction. The compounds of the formula I are intermediates for the preparation of synthetic pyrethroids.
申请公布号 IE47130(B1) 申请公布日期 1983.12.28
申请号 IE19780001441 申请日期 1978.07.18
申请人 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 发明人
分类号 C07C69/74;A01N;A01N53/10;B01J27/00;B01J27/02;C07B61/00;C07C;C07C67/22;C07C69/743 主分类号 C07C69/74
代理机构 代理人
主权项
地址