发明名称 PRODUCTION OF PARA-SUBSTITUTED HALOGENATED BENZENE DERIVATIVE
摘要 <p>PURPOSE:To obtain the title compound useful as an intermediate for raw materials of various compounds, economically in high yield, without producing by-products such as o-substituted halogenated benzene derivative, by using leucite as a catalyst in the halogenation of benzene or its derivative. CONSTITUTION:The objective compound is produced by reacting benzene and/or a benzene derivative with a halogenation agent in the presence of leucite as a catalyst, preferably in a liquid phase preferably at 0-200 deg.C, especially at 20-150 deg.C. The leucite used as a catalyst is a silicate having three-dimensional skeleton structure and is used by calcining, as necessary after drying, in the stream of air or an inert gas such as nitrogen or helium. The reaction can be preferably performed by batch process, semi-batch process or continuous process and the catalyst is used in the form of a fixed bed or suspended bed. A simple substance of halogen is used as the halogenation agent.</p>
申请公布号 JPH01128947(A) 申请公布日期 1989.05.22
申请号 JP19870284308 申请日期 1987.11.12
申请人 TOSOH CORP 发明人 HIRONAKA TOSHIO;MIYAKE TAKANORI;SEKIZAWA KAZUHIKO
分类号 C07B61/00;B01J21/16;C07C17/00;C07C17/12;C07C25/02;C07C25/08;C07C67/00 主分类号 C07B61/00
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