发明名称 Preparation of beta-aryl alcohols
摘要 beta -Aryl alcohols for the general forumla I <IMAGE> I where R1, R2 and R3 are identical or different and each is hydrogen, C1-C20-alkyl, C5-C7-cycloalkyl, aryl, C7-C12-aralkyl or C7-C12-alkaryl, n is 0, 1, 2, 3 or 4, or where two adjacent R1's are linked to form a 5- or 6-membered ring, are prepared by reacting an aromatic of the formula II <IMAGE> II with an alkylene oxide of the formula III <IMAGE> III where R1, R2 and R3 have the abovementioned meanings, in the presence of a Friedel-Crafts catalyst, by carrying out the reaction in the presence of a titanium(IV) alcoholate at from -20 DEG to +40 DEG C. in the presence or absence of a solvent.
申请公布号 US4820882(A) 申请公布日期 1989.04.11
申请号 US19880144169 申请日期 1988.01.15
申请人 BASF AKTIENGESELLSCHAFT 发明人 ECKHARDT, HEINZ;EGGERSDORFER, MANFRED
分类号 B01J31/26;B01J31/00;C07B61/00;C07C27/00;C07C29/132;C07C29/36;C07C33/18;C07C33/20;C07C33/34;C07C67/00;(IPC1-7):C07C31/135;C07C33/22 主分类号 B01J31/26
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