| 摘要 |
<p>A process for fabricating worked superconducting ceramics material composed essentially of a yttrium-including rare earth element, an alkaline earth metal, copper and balance oxygen and unavoidable impurities, and optionally containing a metal originating from an oxygen supply agent, comprising performing hot isostatic press treatment to apply compression force to an object to be compressed at a predetermined timing during the fabrication of worked superconducting ceramics material comprising the steps of: (A) providing starting powder composed of: (i) a member selected from the group consisting of: (1) a mixt powder composed of powders of component oxides: (1-1) a yttrium-including rare earth element oxide, (1-2) an alkaline earth metal oxide, and (1-3) copper oxide, and having a composition substantially the same as that of a contemplated superconducting ceramics, (2) a mixt powder composed of powders of: (2-1) a partial compound between any two of the component oxides constituting a contemplated supercoductive ceramics secelected from (1-1), (1-2) and (1-3), and (2-2) the rest of the component oxides selected from (1-1), (1-2) and (1-3), and having a composition substantially the same as that of a contemplated superconducting ceramics, (3) powder of a superconducting ceramics composed essentially of a yttrium-including rare earth element, an alkaline earth metal, copper and balance oxygen and unavoidable impurities, (4) a mixt powder composed of at least two members selected from the mixt powders (1), (2) and (3); and (ii) optionally an oxygen-supply agent; (B) placing the starting powder in a metal casing, and sealing the metal casing; (C) optionally heat-treating the starting powder in the metal casing when the starting powder is the mixt powder (1-1), (1-2) or (1-4) at a temperature sufficient for calcining the starting powder; (D) working the metal casing containing the starting powder optionally heat-treated according to the step (C) above into an article having a predetermined form; and (E) optionally heat-treating the article at a temperature of from 300 DEG C to 950 DEG C; the timing of perfoming the hot isostatic press treatment being selected from (i) after the step of (B), (ii) after the step of (C), and (iii) after the step of (D).</p> |
