| 摘要 |
A particulate solid is formed from a compound of the general formula Mg(OR)xX(2-x) where R is R' or COR', R' is a hydrocarbyl group, X is a halogen atom and x is greater than 0 up to 2, the particles of the solid being essentially spherical. The solid can have a surface area of at least 15 m<2>/g, and the surface area may be at least 50 m<2>/g. The solid is porous and may be capable of absorbing at least 0.6 cm<3> of ethanol per gramme of solid. The particulate solid may be obtained by spray drying a non-particulate material, preferably by comminuting the non-particulate material in the presence of a liquid medium, and desirably an attrition inhibitor, and spray-drying the comminuted mixture. The particulate solid can be reacted with a transition metal compound such as titanium tetrachloride and preferably with a Lewis Base compound such as the ester of an aromatic carboxylic acid. The transition metal composition obtained is useful for the production of olefin polymerisation catalysts of high activity and stereospecificity. The polymers obtained have an essentially spherical particle form and are porous, for example having a porosity of at least 0.2 cm<3>/g as measured by mercury porosimetry. The polymers typically have a mean particle size of at least one millimetre.
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