摘要 |
PURPOSE:To modify surface properties such as adhesiveness, wettability, coating properties, dyeability, etc., by treating a high polymer material by plasma and then reacting the material with a carboxylic acid polymerizable monomer and a diene polymerizable monomer. CONSTITUTION:(A) A high polymer material (preferably fibrous polyparaphe nylene terephthalamide, etc., useful as a compounding and reinforcing material for resin and rubber) is treated by plasma and then is reacted with (B) a carboxylic acid polymerizable monomer (preferably acrylic acid) and a diene polymerizable monomer (preferably butadiene, isoprene, etc.,). A mixed solution or mixed emulsion preferably containing 0.05-10pts.wt. carboxylic acid monomer based on 1pt.wt. diene monomer is brought into contact and reacted with the high polymer material after the treatment A at 40-210 deg.C and the material is optionally washed and dried to modify the surface.
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