发明名称 PURIFICATION OF GLYCIDOL
摘要 PURPOSE:To improve the stability of the titled substance useful as intermediate raw material for various chemicals, by reacting allyl alcohol with hydrogen peroxide to obtain glycidol containing glycidoaldehyde as a by-produced impurity and treating the glycidoaldehyde in glycidol with a reducing agent. CONSTITUTION:Glycidol is produced by reacting allyl alcohol with hydrogen peroxide in the presence of preferably 3,000-7,000ppm of a catalyst (e.g. tungstic acid, etc.). In the above process, glycidoaldehyde existing in glycidol as a by- produced impurity is treated with preferably 500-1,000ppm of a reducing agent (e.g. sodium borohydride).
申请公布号 JPS63162682(A) 申请公布日期 1988.07.06
申请号 JP19860308717 申请日期 1986.12.26
申请人 DAICEL CHEM IND LTD 发明人 AOYAMA HIROSHI
分类号 C07D301/32;C07D303/14 主分类号 C07D301/32
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