摘要 |
FIELD: production of pure phosphoric acid and calcium monohydrophosphate. ^ SUBSTANCE: proposed method includes decomposition of phosphate ore by first hydrochloric acid solution at concentration not exceeding 10 mass-%, separation of liquid decomposition product into insoluble solid phase containing admixtures and separate aqueous phase containing phosphate, chloride and calcium ions in form of solution, neutralization of aqueous phase separated from liquid decomposition product by adding calcium compound for obtaining insoluble settled-out calcium phosphate by means of phosphate ions, separation of neutralized aqueous phase into aqueous phase containing calcium and chloride ions in form of solution and settled solid phase on base of water-insoluble calcium phosphate and dissolving of at least part of separated settled solid phase in second aqueous hydrochloric acid solution containing hydrochloric acid in the amount exceeding its content in first hydrochloric acid solution, thus forming aqueous solution containing phosphate, chloride and calcium ions extracted by organic extracting agent at extraction in "liquid-liquid" system. Proposed method makes it possible to avoid fine grinding or roasting of ore. ^ EFFECT: enhanced efficiency of extraction for production of pure concentrated phosphoric acid solution with no contamination of surrounding medium. ^ 24 cl, 2 dwg, 1 tbl, 4 ex
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