| 摘要 |
A trioxane polymer is continuously produced with a continuous stirring-mixing apparatus. The apparatus includes two mutually parallel rotational shafts, a large number of paddles mounted on each rotational shaft and a barrel having an inside wall surface along the circular surface traced by the respective paddles, as they rotate. Thus, the barrel has a cross-section in the shape of two circles concentric with the two rotational shafts, which overlap each other. The apparatus is also provided with a temperature controlling jacket. In the operation of the apparatus, a material mixture of trioxane, catalyzer, other copolymerizable comonomers, as the case may be, and additives, is continuously fed in through a material supply port located at one end thereof, then, the material mixture is subjected to polymerization or copolymerization reaction, while being stirred by turning the aforementioned rotational shafts in an opposite direction to each other and, thereafter, the polymers or copolymers of trioxane are taken out as fine granules through a discharge port located at the other end thereof. The method is characterized in that at least one set of paddles of a sectional shape which meets a requirement that when a pair of paddles facing each other are turned in different directions around their rotational axes, the clearance between them shall be kept always as narrow as less than 3/100 of the barrel ID, are mounted on each shaft, adjoining each other, and the different direction turning is made in a state such that the clearance between the farthest part from the rotational axis of said paddle and the inside wall of the barrel are always maintained as narrow as less than 3/100 of the barrel ID.
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