摘要 |
PURPOSE:To obtain a membrane type thermal head having high heat resistance, long life and high inherent resistivity and adjustable in temp. coefficient, by providing a heat generating resistor membrane based on a high m.p. metal, aluminum and nitrogen to substrate having a heat insulating layer and forming an abrasion resistant protective film on the surface thereof and, further connecting a power supply electrode to said resistor membrane. CONSTITUTION:A glaze layer 2 is formed to the surface of a glazed ceramic substrate 1. The glaze layer 2 comprises oxide corresponding to the glaze of porcelain and contains silicon oxide and aluminum oxide. A membrane heat generating resistor 3 is formed on the glaze layer 2 in a film form and a power supply electrode 4 is further formed in a film form and, at last, an abrasion resistance protective film (e.g., an Al-O-N system, an Al-O system, an Al-Si-O system) 6 is formed in a film form. The heat generating resistor 3 is an oxide containing aluminum and a high m.p. metal (at least one of Ti, Mo, W, Hf, Ni, V, Zr, La, Cr, Ta, Fe and Co). This high m.p. metal is used alone or in combination thereof and largely varies in the resistivity range of 10<7>-10<2>muOMEGAcm of the heat generating resistor in both cases. |