发明名称 OPTICALLY ACTIVE CYCLOPENTENONE ESTER COMPLEX AND ITS PREPARATION
摘要 NEW MATERIAL:An optically active cyclopentenone ester complex which is obtained from an optically active 2-cyclopentene-4-one-1-ol ester of formula I (R is aliphatic hydrocarbon which may be substituted with halogen) and an optically active 1,6-diphenyl-2,4-hexadiyne-1,6-diol derivative of formula II (R' is halogenated phenyl, lower alkylphenyl, naphthyl, tert.-lower alkyl). EXAMPLE:1:1 complex from (+)-1,6-diphenyl-1,6-di(o-chlorophenyl)-2,4- hexadiyne-1,6-d-iol and (+)-2-cyclopentene-4-one-1-ol n-butyrate. USE:An intermediate of medicines and agricultural chemicals. PREPARATION:A compound of formula I and another compound of formula II is mixed in an organic solvent to give the titled compound.
申请公布号 JPS62142130(A) 申请公布日期 1987.06.25
申请号 JP19860040642 申请日期 1986.02.26
申请人 SUMITOMO CHEM CO LTD;TODA FUMIO 发明人 TODA FUMIO;MINAMII MASAYOSHI
分类号 C07B53/00;C07B31/00;C07B57/00;C07C27/00;C07C29/00;C07C33/28;C07C33/48;C07C67/00;C07C67/28;C07C67/52;C07C67/60;C07C69/013;C07C69/145;C07C69/24;C07C69/63;C07C69/708 主分类号 C07B53/00
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