摘要 |
NEW MATERIAL:A compound shown by formula I [X1 and Y1 are H or alkyl; X2 and Y2 are H, cyano, -CH2Q (Q is phenylsulfinyl, alkylsulfonyloxy, alkylcarbonylmethylthio, dialkylamino, alkoxycarbonyloxy, dialkoxydithiophosphonomethyl); Z1 and Z2 are O or S; R1 and R2 are alkyl; one of X2 and Y2 is cyano or -CH2Q]. EXAMPLE:S-sec-Butyl O-ethyl(5-phenylsulfinylmethyl-2-oxo-3-oxazolidinyl) phosphonothiolate. USE:A controller for harmful organisms against insects, acarids and nematodes. PREPARATION:A compound shown by formula II is reacted with a phosphoric acid diester chloride compound shown by formula III at preferably -80 deg.C-room temperature in the presence of an acid acceptor such as n-butyllithium, etc., and a solvent such as hexane, etc.
|