发明名称 |
Method for preparing transition metal component of Ziegler-Natta catalysts |
摘要 |
A method for preparing Ziegler catalysts is disclosed wherein a mixture (A) containing the product resulting from mixing in an inert hydrocarbon diluent (1) a hydrocarbon soluble magnesium alkyl compound in said hydrocarbon solvent, (2) an aliphatic alcohol or carbon dioxide and (3) a titanium compound is reacted with (B) a reducing halide source in said hydrocarbon solvent. Components (A) and (B) are mixed at a constant initial temperature. When the magnesium concentration in component (A) and the metal concentration in component (B) are relatively low, the resultant polymer has a relatively narrow particle size distribution whereas when said concentration is relatively high, the resultant polymer has a relatively broad particle size distribution. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively low, the resultant polymer has a relatively small average particle size. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively high, the resultant polymer has a relatively large average particle size.
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申请公布号 |
US4661465(A) |
申请公布日期 |
1987.04.28 |
申请号 |
US19860894406 |
申请日期 |
1986.08.07 |
申请人 |
THE DOW CHEMICAL COMPANY |
发明人 |
FUENTES, JR., RICARDO;MARCHAND, GARY R.;MEISKE, LARRY A. |
分类号 |
C08F4/62;C08F10/00;(IPC1-7):C08F4/62;C08F4/64;C08F4/68 |
主分类号 |
C08F4/62 |
代理机构 |
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主权项 |
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地址 |
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